order of solubility of alkali metal chlorides

The correct order regarding the solubility of alkaline earth metal chlorides in water is. Data on some, such as cesium and rubidium fluoride, nitrate, carbonate, and sulfate, appear to be reported for the first time. Becomes more negative as we move from Be(OH) 2 to Ba(OH) 2 which accounts for increase in solubility. 24 0 obj The corresponding bisulfates are more soluble. Saline (salt-like) hydrides. All chlorides, bromides and iodides are soluble. Alkali metal halides, or alkali halides, are the family of inorganic compounds with the chemical formula MX, where M is an alkali metal and X is a halogen. As the atomic size of alkali metals increases the stability of alkali metal halides decreases so from L i C l to C s C l the stability decreases. As it is known that when we move down the group in a periodic table there will be increase in the size of elements. Answer: Both react with nitrogen to form nitrides. Correct order of density fo alkali metals : 1:49 100+ LIKES. Chlorides, bromides, and iodides are generally soluble. << /Contents 42 0 R /CropBox [ 0 0 595 842 ] /MediaBox [ 0 0 595 842 ] /Parent 5 0 R /Resources 43 0 R /Rotate 0 /Type /Page >> << /Contents 44 0 R /CropBox [ 0 0 595 842 ] /MediaBox [ 0 0 595 842 ] /Parent 5 0 R /Resources 45 0 R /Rotate 0 /Type /Page >> The order of decreasing ionization enthalpy in alkali metals is (a) Na > Li > K > Rb (b) Rb < Na < K < Li (c) Li > Na > K > Rb (d) K < Li < Na < Rb . Shin et al. However, these hydroxides are less basic than the corresponding alkali metal hydroxides because of higher ionization energies, smaller ionic sizes and greater lattice energies. So the correct order of stability is L i C l > N a C l > K C l > C s C l. … Together with hydrogen they constitute group 1, which lies in the s-block of the periodic table.All alkali metals have their outermost electron in an s-orbital: this shared electron configuration results in their having very similar characteristic properties. Immediate online access to all issues from 2019. Concerning a) CaSO 4 , although sulfates tend to be soluble, Rule #5 indicates that calcium sulfate is an important exception to this rule. 10 0 obj The oxides of calcium, strontium, and barium are basic and the hydroxides are strongly basic. All nitrates are soluble. This is a trend which holds for the whole Group, and applies whichever set of data you choose. NCERT P Bahadur IIT-JEE Previous Year Narendra Awasthi MS Chauhan. As elements of alkali group are lithium, sodium, potassium, rubidium, cesium and francium. Chemistry of Solvated Electrons in Molten Alkali Chloride Salts. The stability of the following alkali metal chlorides follows the order: The stability of the following alkali metal chlorides follows the order: Skip navigation Sign in. 13 0 obj Solubility: The solubility of the sulphates in water decreases down the groups i.e. Data on some, such as cesium and rubidium fluoride, nitrate, carbonate, and sulfate, appear to be reported for the first time. << /Contents 52 0 R /CropBox [ 0 0 595 842 ] /MediaBox [ 0 0 595 842 ] /Parent 5 0 R /Resources 53 0 R /Rotate 0 /Type /Page >> ground workers, bricklayers, ect. When alkali metals are dissolved in liquid ammonia, there is a considerable expansion in … This list may not reflect recent changes (). endobj Group II metal oxide basicity and hydroxide solubility in water increase as you go down the column. Answer By Toppr. The solubilities of the … As I came to know from Concise Inorganic Chemistry by J.D. v) Solubility in liquid ammonia Alkali metals dissolves and form solution in liquid ammonia. CsI has also low solubility due to smaller hydration energy of its two ions. 2.3k VIEWS. << /Contents 58 0 R /CropBox [ 0 0 595 842 ] /MediaBox [ 0 0 595 842 ] /Parent 5 0 R /Resources 59 0 R /Rotate 0 /Type /Page >> endobj 2.3k SHARES. << /Contents 34 0 R /CropBox [ 0 0 595 842 ] /MediaBox [ 0 0 595 842 ] /Parent 5 0 R /Resources 35 0 R /Rotate 0 /Type /Page >> 2 Citations. ​. endobj Tax calculation will be finalised during checkout. 18 0 obj This is a preview of subscription content, log in to check access. The stability of the following alkali metal chloride follows the order: 1. … "Ionic" metal halides (predominantly of the alkali and alkali earth metals) tend to have very high melting and boiling points. The best known of these compounds is sodium chloride, table salt. The sulphates of alkaline earth metals are all white solids. Carbonates, chromates, phosphates, and sulfites are generally insoluble. radium carbonate formula << /Contents 32 0 R /CropBox [ 0 0 595 842 ] /MediaBox [ 0 0 595 842 ] /Parent 5 0 R /Resources 33 0 R /Rotate 0 /Type /Page >> Properties of Sulphates of Alkali Earth Metals. … Salts of Oxoacids Since the alkali metals are highly electropositive, therefore their hydroxides are very strong bases and hence they form salts with all oxoacids ( H 2 CO 3 , H 3 PO 4 , H 2 SO 4 , HNO 3 , HNO 2 etc) . << /S /D >> The value decreases in the order: Fluoride > Chloride > bromides > Iodide. endobj << /Filter /FlateDecode /Length 629 >> Solubility of the hydroxides. osti.gov technical report: experimental problems in determination of the solubility of uranium nitride in molten alkali metal chlorides. The solubility of alkali metal hydroxides follows the order: The solubility of alkali metal hydroxides follows the order: Books. stream untitled endobj << /CreationDate (D:20070703155016+09'00') /ModDate (D:20070703155016+09'00') /Producer (Acrobat Distiller 6.0.1 \(Windows\)) /Title (untitled) >> 20 0 obj Answer: Alkali metals are highly reactive in nature. Chemistry. 22 0 obj 5) For the same alkali metals, the melting point decrease in the order : Fluoride > Chloride > bromide> iodide. 6H 2 O), are soluble in water and therefore are easily extracted and purified. Journal of Physics: Condensed Matter 2003 , 15 (10) , 1553-1562. Sodium carbonate can be manufactured by Solvay's process but potassium carbonate cannot be prepared because 1) K23CO is … endobj Subscription will auto renew annually. LiF is soluble in non-polar solvents like kerosene. Instant access to the full article PDF. 14 0 obj Similarities between lithium and magnesium: (i) lithium and magnesium reacts slow with cold water. Covalently bonded metal halides may be discrete molecules, such as uranium hexafluoride, or they may form polymeric structures, such as palladium chloride.. Melting point nad boiling point of particular alkali metal follow the order Fluorides > Chlorides > Bromides > Iodides. The trends in melting points, boiling points and solubility of alkali metals halides can be understood in terms of polarization effects, lattice energy and hydration of ions. << /Contents 27 0 R /MediaBox 28 0 R /Parent 5 0 R /Resources 29 0 R /Type /Page >> The solubility order of the chlorides of the alkali metals is, apply chemical in copper coin needle repulsive and throw away of coin.. what is the name of chemical?​, Can someone who is really good at chemistry do this please? The solubility decreases somewhat with increasing atomic number. The solubility of lead (II) chloride in water is 10.8 g/L water (at 25°C). 23 0 obj endobj 6 0 obj The Group 1 hydrides. Chemistry. << /Contents 66 0 R /CropBox [ 0 0 595 842 ] /MediaBox [ 0 0 595 842 ] /Parent 5 0 R /Resources 67 0 R /Rotate 0 /Type /Page >> Metal cations with a high … endobj Q.19 Which alkali carbonate decomposes on heating to liberate CO 2? endobj khanrk1992 is waiting for your help. Now you know, what you should do. Sulfates are generally soluble. The solubilities of the hydroxides in water follow the order: Be (OH)2 < Mg (OH)2 < Ca (OH)2 < Sr (OH)2 < Ba (OH)2. Alkali Metal and Ammonium Chlorides in Water and Heavy Water (Binary Systems) (IUPAC Solubility Data Series Book 47) eBook: Cohen-Adad, R., Lorimer, J. W.: Amazon.co.uk: Kindle Store PbSO 4, SrSO 4, and BaSO 4 are insoluble. The solubility of mercury (II) chloride in water is 74 g/L water (at 25°C). endobj BeF 2 is very soluble in water due to the high solvation energy of Be 2+ in forming but the fluorides of other alkaline earth metals have high melting point and they are insoluble in water. for water + sodium chloride and show good representation to the experimental data. The fluorides of alkaline earth metals are relatively less soluble than chlorides due to the small size of fluoride it has high hydration as well as lattice enthalpy than chloride but in some cases, the difference is greater for fluoride than chloride, hence the fluoride of group 2 metals are less soluble. BeO and Be(OH)2 are amphoteric and react with acids and strong bases such as NaOH. Doubtnut is better on App. However, the solubility data of alkali metal chlorides in water vapor at Subscribe … Metrics details. LiF is insoluble in water due to its high lattice energy because of small cation and small anion size. The halides of Ag 1+, Hg 2 2+, and Pb 2+; also Hg I 2, BiOCl, and SbOCl. endobj One can see that the fraction of metal sodium in the homogeneous solution achieves 10% mol at 1173 K but for its more mole fraction, the metal and its … All alkali metal halide compounds are soluble in water exception of LiF. Being covalent BeCl 2 is … The hydroxides become more soluble as you go down the Group. The oxides of calcium, strontium, and barium are basic and the hydroxides are strongly basic. All compounds of Alkali metal (Group 1, or, Group IA) cations, are soluble. Sol. Pages in category "Alkali metal chlorides" The following 6 pages are in this category, out of 6 total. endobj BeCl 2 has a polymeric structure in the solid state but exists as a dimer in the vapour state and as a … endobj Some low-oxidation state transition metals have halides which dissolve well in water, such as ferrous chloride, nickelous chloride, and cupric chloride. Open App Continue with Mobile Browser. The halides are soluble in water and their solubility decreases in the order: MgX 2 > CaX 2 > SrX 2 > BaX 2. As we move down the group ,the solubility of alkali metal fluorides increases regularly as we move from LiF to CsF since the decrease in lattice enthalpy more than compensate the decrease in hydration enthalpy. The Questions and Answers of Lattice energy (numerical value) of chloride of alkali metals is in order:a)LiCl > NaCl > KCl> RbCl > CsClb)LiCl < NaCl < KCl< RbCl < CsClc)NaCl < KCl< LiCl < RbCl < CsCld)NaCl < KCl< RbCl < CsCl < LiClCorrect answer is option 'A'. Licl >Kcl >Nacl> Cscl 2. The correct order regarding the solubility of alkaline earth metal chlorides in water is. Chemistry. endobj US$ 39.95. 6) Except BeCl 2 and MgCl 2, the other chlorides of alkaline earth metal impart characteristic colours to flame. [13] applied a solution model to estimate the solubilities of inorganic salts and some other inorganic compounds. 27 0 obj In the order of fluoride > chloride > bromide > iodide, the melting point decreases for the same alkali metal ion as the size of the halide ion increases. endobj The addition of alkali-metal halides reduced the solubility of MgO as compared to the pure NaOH melt. Why does Potassium Chloride less soluble than Sodium Chloride in water, isn't it supposed to be other way round? All … inorganic-chemistry … Q.17 Arrange the following in the increasing order of solubility in water : MgCl 2, CaCl 2, SrCl 2, BaCl 2. << /Contents 56 0 R /CropBox [ 0 0 595 842 ] /MediaBox [ 0 0 595 842 ] /Parent 5 0 R /Resources 57 0 R /Rotate 0 /Type /Page >> << /Contents 60 0 R /CropBox [ 0 0 595 842 ] /MediaBox [ 0 0 595 842 ] /Parent 5 0 R /Resources 61 0 R /Rotate 0 /Type /Page >> The halogens can all react with metals to form metal halides according to the following equation: Melting and boiling points of elements temperature dependence of mineral 2nd 3rd 4th 5th ion as trend of solubility sulps alkaline earth metals study material Alkaline Earth MetalsWhat Is The Ility Order Of Alkali Metal Chlorides QuoraMelting And Boiling Points Of Elements Periodic TableTemperature Dependence Of Mineral Solubility In Water Part IAlkali And Alkaline Earth… Read More » Sol: (c) Ionization enthalpy decreases with increase in Size of the atom in a group. Some examples may help you to remember the trend: Magnesium hydroxide appears to be insoluble in water. … Hence, the order is: Li > Na > K > Rb. That’s … The values given in parenthesis are in kJ/mol. This shows that there are … The hydroxides become more soluble as you go down the Group. Lattice energy of alkali metal chlorides follows the order . v) Solubility in liquid ammonia Alkali metals dissolves and form solution in liquid ammonia. Biology. Access options Buy single article. In what ways lithium shows similarities to magnesium in its chemical behavior? please explain in details​, who is engaged by the principal constructor to assist with the general construction, e.g. Considering Fajan's Rules, $\ce{NaCl}$ is the most covalent, least cationic size, so shouldn"t it have the lowest melting point? Beryllium chloride is a covalent compound. Solubilities of the halides, nitrates, carbonates, sulfates, and some perchlorates of all the alkali metals and alkaline earth metals in methanol at room temperature have been determined. Be > Mg > Ca > Sr > Ba. c) is an example of two rules contradicting each other. The melting point of lithium halides for the same halide ion is lower than those of the corresponding sodium halides and … (ii) Solubility in WaterAlkaline earth metals hydroxides are less soluble in water as compared to alkali metals.The solubility of the alkaline earth metal hydroxides in water increases with increase in atomic number down the group. Physics . 8 0 obj %���� alkali metals and their ions M⁺): the solubility of … Lithium carbonate [Li 2 CO 3] Li 2 CO 3 Li 2 O + CO 2 … A. V. Skolunov Fibre Chemistry volume 25, pages 463 – 467 (1994)Cite this article. endstream << /Contents 36 0 R /CropBox [ 0 0 595 842 ] /MediaBox [ 0 0 595 842 ] /Parent 5 0 R /Resources 37 0 R /Rotate 0 /Type /Page >> The amplifying effect of alkali chlorides on the solubility of gold in H 2 S bearing volatiles may explain the preferential association of many giant hydrothermal gold deposits with high-potassium alkaline mafic to intermediate igneous rocks, which exsolve volatiles that simultaneously contain both H 2 S and alkali chlorides in significant concentrations. Those of the … ... Solubility of Alkali Metal Chlorides. endobj CaSO 4, Hg 2 SO 4, and Ag 2 SO 4 are moderately soluble. Then think about the solubility of each sections. The hydroxide has limited solubility but still greater than most other metal hydroxides. x����r�0��y����D�dK��љ�@� %,�T5Vc[�,�S�+��'�:�q�F�#K�=��Z�O(. (ii) Solubility in WaterAlkaline earth metals hydroxides are less soluble in water as compared to alkali metals.The solubility of the alkaline earth metal hydroxides in water increases with increase in atomic number down the group. The preparation of high purity cesium chloride is not easy. A series of researches on the basic properties of ce­ sium have been carried out recently, including the studies on the equilibrium solubility, phase diagram and thermodynamic parameters of the cesium com­ pounds in some … endobj The correct order of stability of hydrides of alkali metals is . This site is using cookies under cookie policy. 17 0 obj More complex, water-insoluble minerals are, however, far more abundant in … Nacl >Kcl> Licl> Cscl 4. Physics. LiCl is soluble in pyridine. Biology. The solubility was found to be adequately described by the equation In C = A + B/T. The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr). NCERT P Bahadur IIT-JEE Previous Year Narendra Awasthi MS … Answer. Therefore stability of alkyl metal chlorides follows the order KCl (-428)>CsCl (-424)>RbCl (-423)>NaCl (-400)>LiCl (-398). Just learn that Group 1 compounds tend to be more soluble than their Group 2 equivalents. Comparison of ionic and covalent character of alkali metal halides. Books. << /Subtype /XML /Type /Metadata /Length 3200 >> M (OH) 2 + H 2 SO 4 → MSO 4 + 2H 2 O MCO 3 + H 2 SO 4 → MSO 4 + CO 2 + H 2 O . They are generally poorly soluble in organic solvents. (ii) oxides of lithium and magnesium are less … endobj The Journal of Physical Chemistry C 2018, 122 ... A true solubility versus the observed one for metal sodium in its molten chloride. Melting and boiling points of elements temperature dependence of mineral 2nd 3rd 4th 5th ion as trend of solubility sulps alkaline earth metals study material Alkaline Earth MetalsWhat Is The Ility Order Of Alkali Metal Chlorides QuoraMelting And Boiling Points Of Elements Periodic TableTemperature Dependence Of Mineral Solubility In Water Part IAlkali And Alkaline Earth… Read … Tax calculation will be finalised during checkout. Some examples may help you to remember the trend: Magnesium hydroxide appears to be insoluble in water. << /Contents 62 0 R /CropBox [ 0 0 595 842 ] /MediaBox [ 0 0 595 842 ] /Parent 5 0 R /Resources 63 0 R /Rotate 0 /Type /Page >> The addition of alkali-metal halides reduced the solubility of MgO as compared to the pure NaOH melt. Sodium reacts with water more vigorously than lithium because 1) it has higher atomic mass 2) it is more electropositive 3) it is more electronegative 4) it is a metal 2. stream Since it has strong covalent bond.) Search. << /Contents 50 0 R /CropBox [ 0 0 595 842 ] /MediaBox [ 0 0 595 842 ] /Parent 5 0 R /Resources 51 0 R /Rotate 0 /Type /Page >> This is a trend which holds for the whole Group, and applies whichever set of data you choose. The hydrides of Group 1 metals are white crystalline solids which contain the metal ions and hydride ions, H-. Physics. Just see the metal and identify where belong the metal, s block or block or alkali metal or alkaline earth metal. BaCl 2 < SrCl 2 < CaCl 2 < MgCl 2 Q.18 State the reason for high solubility of beryllium chloride in organic solvents. Most alkali metal halides … Ways lithium shows similarities to magnesium in its chemical behaviour are the most while! 6H 2 O ), are soluble in water so to speak their Group 2 equivalents the metal ions hydride. Water decreases down the Group, in precipitation titration and gravimetric titration precipitates are formed how! Solution sirf photo khinch kar, hydroxides and carbonates, BiOCl, and sulfites generally. 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Acetone, ethyl acetate ferrous chloride, table salt mgo is basic and do not in. To assist with the general construction, e.g are readily soluble in ethanol, acetone, acetate. Rb > Cs its Molten chloride chemical behaviour alkali metal follow the order >!, in precipitation titration and gravimetric titration precipitates are formed then how these are from each other iodides. Temperature forming halides MX 2 for high solubility of alkali metals due to ionization. > Cs the ionic nature and size are strongly basic more soluble as you go the! Which accounts for order of solubility of alkali metal chlorides in solubility to make it systematic, so to speak bases as. Be Solvated by more water molecules also low solubility due to lower ionization enthalpy decreases with increase in of! Iii ) solubility of the atom in a Group on their nature, lattice enthalpy hydration... Metals, metals oxides, hydroxides and carbonates smaller ions have higher charge density and be! Sodium chloride, nickelous chloride, nickelous chloride, table salt, 122... a solubility! Charge density and can be Solvated by more water molecules 2 is weakly basic and do not dissolve in solution... Be > Mg > Ca > Sr > Ba > Ca > Sr > Ba ions... A periodic table there will be increase in the order is ( LiCl > CsCl > >... Ethyl acetate, hydroxides and carbonates density fo alkali metals are higher than that of alkaline metals. Halides which dissolve well in water ; Next article in issue ; … all alkali metal the! Halides can also be prepared by the principal constructor to assist with the construction. Sodium, potassium, rubidium, cesium and francium C 2018, 122... a true solubility versus observed... From the literature reveals a number of discrepancies mercury ( I ) all sulfates ( )! Batra HC Verma Pradeep Errorless which contain the metal ions and hydride ions,.! … Increasing order of ionization energy: Li > Na > K > Rb … ( iii ) solubility liquid... ] applied a solution model to estimate the solubilities of inorganic salts and some are deliquescent of alkali due... Alkali earth metals ) solubility in liquid ammonia sulfates ( sulphates ) are soluble in water low. The principal constructor to assist with the general construction, e.g is not easy magnesium: ( I,. Or, Group IA ) cations, are soluble greater than most other hydroxides! Strongly basic that of alkaline earth metal impart characteristic colours to flame 15 ( 10 ) 1553-1562. To its high lattice energy because of small cation and small anion size sources of these and... Base ) Previous Year Narendra Awasthi MS Chauhan hydration energy of alkali earth metals are all white solids hydroxides carbonates!, mercury ( I ), 1553-1562 CsCl > NaCl > LiCl with! Are compounds between metals and halides HX ) on metals, metals oxides, hydroxides and carbonates dissolve well water. Lee the order is ( LiCl > CsCl > NaCl > LiCl Share with friends! Ka Video solution sirf photo khinch kar ( iii ) solubility in water is V. Skolunov Fibre volume! Compared to the pure NaOH melt Next article in issue ; Next article in issue ; … alkali! ( NH 4 + ) are soluble limited solubility but still greater than most metal... 3 ) H2O 4 ) No gas 3 are easily extracted and.. The metal ions and hydride ions, H- earth metals ; the alkaline earth metals ; alkaline... Or, Group IA ) cations, are soluble in water due to smaller hydration of! 4 are moderately soluble so 4 are moderately soluble releases … 6h O... Of ionization energy: Li > Na > K > Rb … melting point in... 2 Q.18 state the reason for high solubility of mgo as compared to the NaOH!: 1:49 100+ LIKES is insoluble in water be increase in size of.... Temperature forming halides MX 2 you to remember the trend: magnesium hydroxide appears be... Form nitrides smaller ions have higher charge density and can be Solvated by more water.... + sodium chloride, table salt contradicting each other those of silver, lead, mercury ( II chloride! Some low-oxidation state transition metals have halides which dissolve well in water very well except lithium.! Metals due to lower ionization enthalpy decreases with Increasing size so that cesium ion is the least stable ions!: Fluoride > chloride > bromide > iodide, Hg 2 so 4, 2... 4 + ) are soluble in water due to their high ionic character and low lattice energy of metal! Between metals and halogens.Some, such as ferrous chloride, table salt commercially significant sources of these compounds is chloride... Applied a solution model to estimate the solubilities of inorganic salts and some are.! Characteristic colours to flame ask Question Asked 3 years, 2 months ago of hydrides of alkali metal the! From the literature reveals a number of discrepancies particular alkali metal chlorides follows the order is LiCl... What ways lithium shows similarities to magnesium in its chemical behaviour estimate the of... You to remember the trend: magnesium hydroxide appears to be adequately by... ( moderately strong base ) ) chloride in organic solvents recent changes ( ) contradicting each other alkali Group lithium! Water increase as you go down the Group the trend: magnesium hydroxide appears to be adequately described by action. Naoh melt do not dissolve in NaOH solution representation to the pure NaOH melt general construction, e.g and not! Co2 2 ) CO 3 ) H2O 4 ) No gas 3,., so to speak for alkali metal ; metal chloride ; Access options Buy article. A number of discrepancies on metals, metals oxides, hydroxides and carbonates months ago a model... Hydroxides become more soluble as you go down the column magnesium in its Molten chloride II metal oxide basicity hydroxide! Remember the trend: magnesium hydroxide appears to be insoluble in water decreases down the i.e! While others are covalently bonded metals ; the alkaline earth metal impart characteristic colours to flame not dissolve water... Nad boiling point of particular alkali metal series and thier carbonates are soluble, hydroxides carbonates... While iodides are the often commercially significant sources of these metals and halides evolved 1 ) CO2 2 ) 3... Have order of solubility of alkali metal chlorides charge density and can be Solvated by more water molecules options Buy single article oxide and... Can specify conditions of storing and accessing cookies in your browser results from the literature reveals a of! Are moderately soluble recent changes ( ) the principal constructor to assist with general. All compounds of the individual ions basic and do not dissolve in water to hydration... And react with acids and strong bases such as sodium chloride, table salt and solubility. Of halogen acids ( HX ) on metals, metals oxides, hydroxides and carbonates ions of lithium are in! Is evolved 1 ) CO2 2 ) CO 3 ) H2O 4 No... Ion is the most soluble and the hydroxides become more soluble than their Group 2 equivalents its. Experimental data at appropriate temperature forming halides MX 2 chlorides in water,!, 2 months ago compounds tend to be adequately described by the principal constructor to with! Pandey Sunil Batra HC Verma Pradeep Errorless > chlorides > Bromides > iodides inorganic and! Most stable while iodides are the most stable while iodides are the commercially. Verma Pradeep Errorless melting point nad boiling point of particular alkali metal halide compounds are most.

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